All-dielectric nanoantennas remain chemically non-invasive, they cause no effect on the studied analytes and reactions.
Credit: FEFU press office
Scientists of Far Eastern Federal University (FEFU) in collaboration with colleagues from Far Eastern Branch of Russian Academy of Sciences (FEB RAS), ITMO University and Swinburne University of Technology (Australia) developed a method for efficient mass production of silicon-germanium fully alloyed nanoantennas. On their basis, optical biosensory platforms and next-generation chemical sensors for fast and accurate tracing of viruses, pollutions, explosives, etc. at low concentrations are expected to appear. Related paper was published in Nanoscale.
To fabricate all-dielectric (AD) optical nanoantennas, scientists proposed a facile technology based on a temperature-assisted dewetting of commercial silicon-on-insulator (SOI) substrates at 800°C in high vacuum. Such treatment of SOI substrate leads to the formation of silicon nanodrops, which can be used as optical nanoantennas, amplifying the signals from various adsorbed molecules. Scientists have shown that the deposition of Ge in the process of SOI dewetting allows producing alloyed nanoparticles with unique properties. Such nanoantennas allow to identify adsorbed molecules as well as to access and control the local temperature at high accuracy and resolution in the process of measurement.
“It’s very useful to know the local temperature because in the process of measurement both the nanoantennas and the adsorbed analyte molecules are exposed with intense laser radiation which causes their heating. At the same time, most organic molecules degrade at rather low temperatures around 130-170°C, i.e. in the process of measurement one can simply burn them up before getting a useful signal. Such useful temperature-feedback modality cannot be realized with plasmonic nanoantennas commonly used to design biosensors. All-dielectric nanoantennas provide a reliable way to achieve this feature as the measured characteristics spectrum of the analyte molecules already contains all information required to determine the local temperature of the “nanoantenna-molecule” system.” Said Aleksandr Kuchmizhak, a researcher in the FEFU Center for Virtual and Augmented reality.
“By controlling the concentration of germanium in the alloyed silicon nanoparticles, one can tailor their properties; in particular, control their resonant optical characteristics, as well as the light-to-heat conversion efficiency. This is very useful for studying of various chemical processes and reactions induced by laser radiation.” Reported Evgeny Mitsai, a researcher at Institute of Automation and Control Processes and Institute of Chemistry, FEB RAS.
The scientist emphasized that by using all-dielectric nanoantennas one can study in details the temperature-mediated effects in laser-induced chemical reactions at high temporal resolution. Moreover, all-dielectric nanoantennas remain chemically non-invasive, i.e. their presence — unlike the presence of the plasmonic-based nanoantennas — causes no effect on the studied analytes and reactions.
Until today, the mass production of all-dielectric nanoantennas was difficult. Commonly used electron-beam lithography was too expensive and time-consuming. The technology proposed by FEFU scientists in collaboration with their colleagues from the FEB RAS, ITMO University, universities of Australia and Tunisia, allows getting over this limitation.
FEFU run a priority research project “Materials” engaged a group of talented physicists, chemists, biologists, and materials scientists, most of which are young scientists under 35 years old. Among other things, researchers actively study novel promising nanomaterials and technologies for next-generation sensory systems as black silicon and laser-textured PTFE.
The study was supported by Russian Science Foundation (RSF), grant 18-79-10091
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