Chameleon materials: The origin of color variation in low-dimensional perovskites

Some light-emitting diodes (LEDs) created from perovskite, a class of optoelectronic materials, emit light over a broad wavelength range. Scientists from the University of Groningen have now shown that in some cases, the explanation of why this happens is incorrect. Their new explanation should help scientists to design perovskite LEDs capable of broad-range light emission. The study was published in the journal Nature Communications on 11 May.

Low-dimensional (2D or 1D) perovskites emit light in a narrow spectral range and are therefore used to make light-emitting diodes of superior colour purity. However, in some cases, a broad emission spectrum at energy levels below the narrow spectrum has been noted. This process has attracted great interest as it could be used to produce white light LEDs more easily compared to the processes that are currently being used. To design perovskites for specific purposes, however, it is necessary to understand why some perovskites produce broad-spectrum emissions while others emit a narrow spectrum.

Quantum confinement

Perovskites are a versatile group of materials with a very distinctive crystal structure, known as the perovskite structure. In an idealized cubic unit cell, anions form an octahedron around a central cation while the corners of the cube are occupied by other, larger cations. Different ions can be used to create different perovskites.

In hybrid perovskites, the cations are organic molecules of different sizes. When the size exceeds a certain dimension, the structure becomes two-dimensional or layered. The resulting quantum confinement has large consequences for the materials’ physical properties and, in particular, for the optical properties.

Emissions

‘There are many reports in the literature where, in addition to the narrow emission of these low dimensional systems, there is a broad low energy spectrum. And this is thought to be an intrinsic property of the material,’ says Maria Loi, Professor of Photophysics and Optoelectronics at the University of Groningen. It has been proposed that the vibrations of the octahedron’s atoms can ‘trap’ an excited stated in a self-trapped exciton, or self-trapped excited state, causing the broad-spectrum photoluminescence, especially in these two-dimensional systems and in systems where the octahedrons are isolated from each other (zero-dimensional).

However, observations made in Loi’s laboratory appear to contradict this theory, says Simon Kahmann, a postdoctoral researcher in her team. ‘One of our students studied single crystals of a lead-iodide-based 2D perovskite and noticed that some crystals emitted green light and others emitted red light. This is not what you would expect if the broad red emission were an intrinsic property of this material.’

Colour

The research team proposed that defects in these perovskites could change the colour of emitted light,. Therefore, they decided to test the mainstream interpretation with an ad hoc experiment. Loi: ‘In the accepted theoretical explanation, the excitations should be larger than the bandgap to produce broad emission.’ The bandgap is the energy difference between the top of the valence band and the bottom of the conduction band.

Using laser light of different colours, and therefore of different energies, they studied the emission of the crystals. ‘We noted that when we used photons below the bandgap energy, the broad emission still occurred,’ says Loi. ‘This should not have happened according to the mainstream interpretation.’

Consequences

Their explanation is that a defect state with an energy level inside the bandgap is governing the broad emission and the large colour variation of the crystals. ‘We think that it is a chemical defect in the crystal, probably related to iodide, which causes states inside the band gap,’ says Kahmann. Thus, the broad emissions are not an intrinsic property of the material but are caused by an extrinsic effect. Kahmann: ‘At this point, we cannot totally rule out that this is a quirk of lead iodide perovskites but it is likely to be a general property of low-dimensional perovskites.’ This finding has profound consequences, explains Loi: ‘If we want to predict new and better compounds that broadly emit light, we need to understand the origin of this emission. We should not be tricked by this chameleon.’

Simple Science Summary

Just over 10 years ago, a class of materials moved into the spotlight of scientific research. These materials can convert light into electricity or electricity into light: hybrid perovskites. These can be used in solar cells, detectors of light or X-rays, but they can also be used as light-emitting diodes. Some perovskites emit light over a narrow wavelength band while others produce broadband emissions that could be used to produce white light. Scientists from the University of Groningen have now shown that the broad emission in 2D lead iodide perovskites is not an intrinsic property of the material. This means it is not very efficient. This means that optical investigations of this class of materials should be interpreted with care.

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Reference: Simon Kahmann, Eelco K. Tekelenburg, Herman Duim, Machteld E. Kamminga and Maria A. Loi: Extrinsic nature of the broad photoluminescence in lead iodide-based Ruddlesden-Popper perovskites. Nature Communications, 11 May 2020