In the relentless pursuit of next-generation energy storage, lithium-metal batteries have long been hailed as the ultimate solution due to their unparalleled energy density. However, the notoriously unstable nature of lithium metal anodes, primarily due to their extreme reactivity with conventional liquid electrolytes, has posed significant challenges to their practical application. A groundbreaking study led by Li, Kou, Nguyen, and their colleagues promises to redefine the landscape of lithium-metal battery technology by unveiling a novel strategy that fosters a remarkably stable solid–electrolyte interphase (SEI), thereby enabling long-lasting lithium-metal batteries with extraordinary performance metrics.
The fragility of lithium metal anodes stems from their tendency to form dendrites and react vigorously with liquid electrolytes, which degrade the anode surface and cause capacity fading and safety risks. Central to mitigating these issues is the formation of a robust SEI—a passivating layer that protects the lithium surface while allowing lithium ions to pass through. Traditionally, achieving a stable SEI has been a formidable hurdle because the interphase forms spontaneously via electrolyte decomposition, leading to a disordered and brittle layer incapable of enduring prolonged cycling.
Addressing this challenge, the research introduces a progressive dual-passivation polymer coating that offers a transformative approach to SEI engineering. Unlike conventional methods that rely solely on electrolyte additives or artificial SEI layers, this strategy leverages a synthesized copolymer coating that not only chemically passivates the lithium metal surface but also modulates the ionic environment in the electrolyte. This dual functionality facilitates a meticulously controlled formation of an SEI with unprecedented chemical and structural integration, overcoming the long-standing instability plaguing lithium metal anodes.
.adsslot_UH2d8wkSTz{width:728px !important;height:90px !important;}
@media(max-width:1199px){ .adsslot_UH2d8wkSTz{width:468px !important;height:60px !important;}
}
@media(max-width:767px){ .adsslot_UH2d8wkSTz{width:320px !important;height:50px !important;}
}
ADVERTISEMENT
At the heart of this innovation is the polymer’s ability to tailor lithium-ion solvation structures within a binary salt carbonate electrolyte. Through selective anion decoordination—a process where the copolymer influences the binding of anions in the electrolyte—the coating guides the decomposition pathway to form a chemically integrated SEI. This dual-passivation mechanism leads to a unique bilayer SEI architecture: an outer chemical passivation layer rich in lithium fluoride (LiF), derived from the polymer coating, and an inner layer abundant in lithium oxide (Li₂O), originating from electrolyte decomposition. The synergy of these layers combines chemical stability with mechanical robustness.
This integrated SEI composition is crucial since LiF has been identified as a highly effective passivating species, known for its chemical inertness and high ionic conductivity, which helps minimize continuous side reactions at the anode surface. Meanwhile, Li₂O contributes to the mechanical integrity of the SEI, preventing dendrite proliferation by providing a uniform and flexible barrier. This combination ensures not only efficient lithium-ion transport but also long-term electrochemical stability even under strenuous cycling conditions.
Crucially, the dual-passivation coating strategy functions seamlessly in carbonate electrolytes—a class of electrolytes widely used in commercial lithium-ion batteries due to their stability and safety profiles, yet traditionally considered detrimental for lithium-metal anodes. By enabling stable cycling in these electrolytes, the work paves the way for more easily adoptable lithium-metal battery configurations without necessitating complex or costly electrolyte formulation changes. This carries profound implications for scaling lithium-metal technology in existing battery manufacturing ecosystems.
Performance tests of lithium-metal batteries employing this coating reveal extraordinary cycling lifetimes. Lithium-metal cells paired with NMC811 cathodes showcased an ability to retain 80% of their initial capacity after a staggering 611 cycles under a constrained electrolyte-to-capacity (E/C) ratio of only 2.0 g Ah⁻¹. Such low E/C ratios are particularly demanding because they simulate practical conditions with limited electrolyte volumes, unlike many laboratory tests that use excess electrolytes to artificially enhance stability. Achieving this in a pouch cell format underscores the industrial relevance and commercial viability of the coating strategy.
The innovation also illuminates subtle mechanistic insights into the SEI formation process. Through advanced characterization techniques and electrochemical testing, the study dissects how the copolymer modulates the local solvation landscape, altering the coordination of lithium ions and electrolyte anions at the molecular level. This control over solvation chemistry is a critical parameter, as it dictates the initial electrochemical reactions that form and evolve the SEI during the very first charge-discharge cycles.
Furthermore, by fostering an integrated and chemically defined SEI, the coating mitigates the continuous electrolyte decomposition and lithium consumption that commonly cause capacity decline and safety hazards such as short circuits from dendritic growth. The stable SEI also preserves the lithium metal surface, hindering the formation of “dead lithium” from isolated, electrically disconnected lithium deposits. This effectively retains the active lithium inventory, directly enhancing the battery’s coulombic efficiency and cycle life.
This research advances the fundamental understanding that SEI formation cannot be considered solely as an electrolyte-centric phenomenon but rather as a dynamic interface influenced by external engineering, in this case, through polymer chemistry. It opens new avenues for designing multifunctional coatings that engage at both the electrode and electrolyte interface, offering more predictable and durable passivation layers that are crucial for next-generation battery architectures.
The broader implications of this study extend beyond just lithium-metal batteries. The principles outlined concerning electrolyte-ion coordination and interphase chemistry have the potential to be generalized across other metal anode systems such as sodium or potassium metal batteries, where interfacial instability remains a primary bottleneck. Additionally, the methodology synergizes well with other emerging strategies including solid-state electrolytes, which could ultimately yield hybrid approaches for ultra-high energy-density and safe batteries.
While the ultimate goal of commercial lithium-metal batteries remains the commercialization of high-capacity, long-lifetime batteries for electric vehicles and grid storage, this research marks a critical milestone. It reduces the gap between lab-scale demonstration and real-world applicability by proving stable cycling with practical electrolyte amounts and standard carbonate electrolytes. Such advancements are essential to integrate lithium-metal anodes into contemporary manufacturing and usage paradigms.
Looking forward, opportunities exist to optimize the copolymer chemistry further to tailor SEI properties based on specific electrolyte formulations and cathode chemistries. Continued efforts combining in situ characterization tools and simulation techniques could provide deeper insights into the interplay of polymer coatings, electrolyte solvation, and interphase evolution over extended cycling under diverse conditions.
In conclusion, this pioneering work underlines the power of chemical and interfacial engineering in overcoming the perennial challenges of lithium-metal anodes. The progressive dual-passivation polymer coating concept elegantly bridges the divide between protecting lithium metal surfaces and tuning electrolyte interactions, achieving a stable and efficient integrated SEI that propels lithium-metal batteries toward practical and scalable deployment. This breakthrough sets a new benchmark in battery science, inspiring future research and accelerating the transition to high-energy, long-lasting energy-storage solutions critical for a sustainable electrified future.
Subject of Research: Stabilization of lithium metal anodes through polymer coatings to form an integrated solid–electrolyte interphase enabling long-cycle life lithium-metal batteries.
Article Title: Long-cycling lithium-metal batteries via an integrated solid–electrolyte interphase promoted by a progressive dual-passivation coating.
Article References:
Li, GX., Kou, R., Nguyen, A. et al. Long-cycling lithium-metal batteries via an integrated solid–electrolyte interphase promoted by a progressive dual-passivation coating. Nat Energy (2025). https://doi.org/10.1038/s41560-025-01803-y
Image Credits: AI Generated
Tags: advanced battery technologydendrite formation in lithium batteriesdual-passivation polymer coatingelectrolyte decomposition challengesenergy density in batteriesimproving battery performance metricslithium metal anodeslong-lasting lithium metal batteriesmitigating safety risks in lithium batteriesnext-generation energy storage solutionsSEI engineering strategiessolid-electrolyte interphase stability
