In the relentless quest for next-generation solid-state electrolytes, researchers have encountered formidable challenges rooted in the fundamental limitations of traditional material design. Conventional strategies focus primarily on doping superionic lattices with compatible dopants, aiming to enhance ionic conductivity while maintaining structural integrity. However, this paradigm is intrinsically constrained by the delicate interplay between dopant ions and host lattices, often resulting in compromised electrochemical performance and limited tunability. In a groundbreaking development, a novel approach termed “solid dissociation” has emerged, dramatically expanding the landscape of solid-state electrolyte design by leveraging the unique properties of halide van der Waals (vdW) materials as solid solvents for salts.
The innovative concept of solid dissociation diverges radically from the entrenched lattice-doping methodologies. Rather than embedding dopants within a rigid crystalline matrix, it involves dissolving salts within crystalline halide vdW materials, which act analogously to solvents but in a solid-state form. This paradigm shift allows the formation of amorphous ion-conductive solids, where the typically immobile lattice framework gives way to a dynamically reconfigurable environment conducive to enhanced ion transport. Such solid solvents provide a previously inaccessible medium facilitating superionic conduction by enabling the dissociation of salts into free, mobile ions under ambient-like solid conditions.
Through a comprehensive screening approach, the researchers have identified an astounding 73 material composites formed via this solid dissociation strategy. More impressively, among these materials, 40 exhibit ionic conductivities that surpass the critical threshold of 10−3 S/cm, a benchmark indicative of practical utility in battery and energy storage technologies. Remarkably, this family of solid electrolytes is versatile, showing effective conduction for monovalent cations such as lithium (Li+), sodium (Na+), silver (Ag+), and copper (Cu+), underscoring the broad applicability of the technique across numerous electrochemical systems.
At the atomic scale, detailed analyses reveal intricate interactions between the solid solvents and dissolved salts. The halide vdW materials facilitate dynamic structural rearrangements within their layered frameworks, permitting efficient ion dissociation and mobility. This dynamic behavior sharply contrasts with the static ionic conduction pathways predominant in doped superionic lattices. These rearrangements involve transient changes in the coordination environment of ions and adaptive modulation of local lattice polarizability, which together lower energy barriers for ion migration, enabling superionic behavior that was previously unattainable in solid systems without liquid components.
One of the most profound insights gleaned from this work is the emergence of consistent ionic environments across a variety of solvent–salt combinations. Despite the seemingly disparate chemical nature of the various halide vdW materials and salts, a universal conduction mechanism manifests. This universality suggests that the fundamental principles governing solid dissociation and ion transport transcend specific compositional details, pointing to an underlying paradigm of ion conduction that closely mimics the molecular solvation and dynamic ion association/dissociation equilibria observed in liquid electrolytes.
By drawing parallels to liquid electrolyte systems, this approach to solid electrolyte design invites a new dimension of compositional tuning. Just as liquid electrolytes benefit from tailored salt concentrations and solvent mixtures to optimize conductivity, electrochemical stability, and thermal properties, solid-state electrolytes engineered via solid dissociation can be precisely adjusted by varying solvent–salt pairs and their respective stoichiometries. This targeted engineering reveals new avenues for customization tailored to specific application requirements, overcoming the longstanding trade-offs inherent in conventional solid electrolyte design frameworks.
The practical implications of solid dissociation-based electrolytes are compelling. Prototypical devices employing these materials demonstrate enhanced operational metrics across critical performance domains. For instance, fast-charging cell prototypes achieve rapid ion transport facilitated by the high ionic conductivity of the amorphous solid electrolytes. Equally notable are low-temperature cells that maintain superior performance, leveraging the dynamic structural flexibility of the solid solvent which mitigates the sluggish ion kinetics typical of rigid lattices under cold conditions.
Another hallmark application is in the realm of high-voltage cells operating at voltages as high as 4.8 V. Here, solid dissociation electrolytes exhibit remarkable electrochemical stability and resilience against oxidative degradation, essential traits for enabling batteries with extended voltage windows and increased energy density. Beyond performance, these materials also showcase enhanced dry-room stability, reducing the stringent environmental controls often necessary for processing and handling moisture-sensitive solid electrolytes. This property not only lowers manufacturing costs but also improves safety profiles by minimizing the risk of moisture-induced degradation.
Cost advantages represent yet another formidable benefit inherent in this solid dissociation platform. Halide vdW materials utilized as solid solvents are generally more economical and readily scalable compared to exotic or rare dopant elements conventionally used in superionic conductors. The reduction in material and processing complexity translates into a viable pathway toward industrial adoption, positioning this strategy as a game-changer for the commercialization of solid-state batteries and other ionically conductive devices.
The discovery of this new class of materials invigorates the fundamental understanding of ion conduction mechanisms in solids. By bridging the conceptual divide between the liquid and solid realms of ionic transport, solid dissociation challenges long-held assumptions about the necessity of crystalline lattice rigidity to facilitate superionic behavior. The resultant soft, amorphous yet mechanically robust electrolytes reconcile the competing demands of stability and ionic mobility, opening unprecedented material design spaces.
The underlying van der Waals bonding within the halide solid solvents plays a critical role in enabling this dissociation and transport flexibility. Unlike strongly covalent or ionic frameworks, van der Waals layered solids possess inherently weaker interlayer forces, permitting facile lattice flexibility and segmental motion essential for ion transport. This particular bonding motif circumvents many of the intrinsic limitations of traditional solid electrolytes, such as brittleness and inflexibility, which impede ion mobility and device integration.
Looking forward, the modularity of the solid dissociation concept unlocks opportunities for integrating a diverse array of functional ions beyond those already demonstrated. Multivalent cations, complex ion species, or even ion pairs with tailored conduction pathways could be conceptualized, harnessing the tunable interaction landscapes inherent to these amorphous solids. Furthermore, coupling macroscale material properties with nanoscale interaction engineering presents a rich frontier for optimizing electrolyte performance at systems levels, from electrode interfaces to full cell assemblies.
As solid-state batteries and related energy storage technologies race toward widespread deployment, innovations such as this solid dissociation approach are indispensable. They offer a credible solution to longstanding bottlenecks in ionic conductivity, interfacial stability, and manufacturability, potentially accelerating the transition away from liquid electrolyte-dependent systems. The universality and adaptability of this method promise to inspire a new generation of research and development trajectories focused on strategic solid electrolyte design.
In sum, the pioneering work on solid dissociation of salts within halide van der Waals materials heralds a new era in solid-state ionics. By reconceptualizing the role of solid solvents and unlocking amorphous ion-conductive phases, this paradigm transcends previous material design limitations and charts a compelling course for future high-performance, scalable, and versatile solid electrolytes. This advance stands to profoundly impact the broader fields of energy storage, electrochemistry, and materials science as it moves from laboratory discovery toward widespread technological application.
Subject of Research: Solid-state electrolytes and superionic conduction mechanisms in halide van der Waals materials.
Article Title: Universal superionic conduction via solid dissociation of salts in van der Waals materials.
Article References:
Yue, J., Zhang, S., Wang, X. et al. Universal superionic conduction via solid dissociation of salts in van der Waals materials. Nat Energy (2025). https://doi.org/10.1038/s41560-025-01853-2
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Tags: amorphous ion-conductive solidsdynamic ion transport mechanismselectrochemical performance improvementhalide van der Waals saltsionic conductivity enhancement techniqueslattice-doping limitationsnext-generation electrolyte designnovel material design strategiessolid dissociation approachsolid solvents for ionic saltssolid-state electrolytessuperionic conduction in van der Waals materials
