Optimizing the properties and microstructure of bulk superconductors

Superconductors are increasingly finding applications in several areas, such as medical imaging techniques, drug delivery systems, energy storage systems, levitation processes, and water purification methods. This can be attributed to their awe-inspiring ability of zero resistance, which ensures the passage of a high amount of current through them, making them suitable for revolutionizing power transmission and transportation.

Magnetic superconductors are commonly synthesized by the “top-seeded melt growth technique” (TSMG). This process, however, has certain drawbacks, such as huge loss of liquid source material while production. This results in changes to the material composition, cracks in the matrix of the formed material, mechanical shortcomings, and even low thermal conductivity. As an alternative, the infiltration growth process, that involves stacking secondary phase pellets on a liquid phase pellet, has been developed for better efficiency in production and applications. Several compositions of a liquid phase have been used for fabricating such bulk superconductors. However, large, single-grain, bulk rare earth (RE) materials, such as RE-123, are still difficult to synthesize using the infiltration growth process.

Now, however, researchers from Japan focus on the use of heavy elements such as gadolinium (Gd), yttrium (Y) and erbium (Er), to synthesize single-grain bulk and ternary superconductors, with liquid stock composition and infiltration growth technique. They also closely analyze the microstructure and properties (superconducting and electromagnetic) of the formed superconducting material (Gd, Y, Er)-123. Their findings reveal huge performance improvement of these ternary bulks, compared to the currently available materials in the market. The study was led by Professor Miryala Muralidhar of the Shibaura Institute of Technology and was made available online in the Journal of Alloys and Compounds.  

First, the researchers evaluated the performance of multiple liquid source starting materials to grow a (Gd, Y, Er)-123 single grain bulk. After ascertaining that Er123 and Ba₃Cu₅O₈ in a 1:1 ratio was the best liquid phase stock material, they proceeded with adding other primary element components, using their respective oxide powders as the starting material.

On evaluating the current flow at critical temperatures, the resulting superconductor was found to allow the flow of highest current density through it, which was 81.09% higher than the previously available materials in this category. Microstructural analysis with scanning electron microscopy revealed a significant reduction in the secondary phase particle size, with a mean particle reduction of 43.13%, compared to the conventional Ba₃Cu₅O₈.

Discussing these results, Prof. Miryala says, “The results are nothing short of impressive. The fact that we were able to fabricate these bulk superconductors in the air, using a cost-effective method, makes this approach highly attractive for large-scale industrial production.”

Moreover, Er123+ Ba₃Cu₅O₈ also yielded the highest critical current density (J_c) of 81.91 kA/cm² in self-field and 28.29 kA/cm² at 1 T for (Gd, Y, Er)-123 ternary system liquid source. 

The greatly enhanced current density in the newly synthesized material is the most remarkable aspect of this research and has huge potential for applications of magnetic superconductors. “These improvements have the potential to revolutionize real-life applications like magnetic levitation, superconducting bearings, electric motors, magnetic drug delivery (MDD) and flywheel energy systems,” says Prof. Miryala.

With such exceptional properties, superconducting materials such as these can greatly enhance and influence power transmission and transportation systems in the near future.  They can also transform multiple industries and become instrumental in combatting climate change, while supporting the Sustainable Development Goals (SDGs) of the United Nations.

In summary, this new approach to synthesizing bulk superconductors has clearly opened the door to mass production of high-performing superconductors and is being deemed as an exciting breakthrough for a wide range of applications.

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Reference

DOI: https://doi.org/10.1016/j.jallcom.2023.170506

About Shibaura Institute of Technology (SIT), Japan

Shibaura Institute of Technology (SIT) is a private university with campuses in Tokyo and Saitama. Since the establishment of its predecessor, Tokyo Higher School of Industry and Commerce, in 1927, it has maintained “learning through practice” as its philosophy in the education of engineers. SIT was the only private science and engineering university selected for the Top Global University Project sponsored by the Ministry of Education, Culture, Sports, Science and Technology and will receive support from the ministry for 10 years starting from the 2014 academic year. Its motto, “Nurturing engineers who learn from society and contribute to society,” reflects its mission of fostering scientists and engineers who can contribute to the sustainable growth of the world by exposing their over 8,000 students to culturally diverse environments, where they learn to cope, collaborate, and relate with fellow students from around the world.

Website: https://www.shibaura-it.ac.jp/en/

About Professor Muralidhar Miryala from SIT, Japan

Dr. Muralidhar Miryala is a Professor at the College of Engineering/Graduate School of Science and Engineering and a member of the Board of Councilor at Shibaura Institute of Technology (SIT). He is also the Chair, OB at World Technology University Network (WTUN). His primary research interests comprise solid state physics and materials science, particularly materials for energy and the environment, such as high-temperature superconductors. He has over 500 publications to his credit and is also the recipient of several awards for his research contributions, including the prestigious 2021 Pravasi Bharatiya Samman Award from the President of India and the SIT Excellent Education Award (2021) by the Chairman of the Board of Directors.

Funding Information
This work was partly supported by the Shibaura Institute of Technology (SIT) Research Center for Green Innovation. Akash Garg Agarwal acknowledges support from SIT for providing financial support for the doctoral program.