New transactions of nonferrous metals society of china study uncovers low-temperature deformation mechanism of pure titanium

Titanium (Ti), often hailed as the wonder metal for its remarkable properties, has many applications in aerospace, marine, and biomedicine industries. Known for their low density, high strength, high ductility, great corrosion resistance, and excellent biocompatibility, Ti and its alloys have been widely studied by numerous researchers for their structural deformation mechanisms at room temperatures. Recently, researchers have focused their efforts on studying the deformation of Ti and its alloys at very low “cryogenic” temperatures (< 77K, the temperature of liquid nitrogen).

Ti and its alloys deform via different mechanisms, including dislocation slips, in which grains of metals slip over each other, and “deformation twinning,” wherein the grains arrange symmetrically around a common grain boundary. A grain, namely a well-defined region within a crystalline material, consists of atoms arranged in a specific, consistent way. The occurrence of deformation twins in Ti alloys depends on the initial texture, strain rate, deformation temperature, and grain size.

Studies have shown that twinning can improve the mechanical properties of materials. Furthermore, cryogenic deformation of commercially pure Ti (CP-Ti) has been shown to trigger deformation twinning, significantly boosting its strength and ductility. However, the exact effects of different deformation mechanisms and grain size on the strength of CP-Ti at cryogenic temperatures have not been fully understood.

To address this gap, a team of researchers from China, led by Assistant Professor Cai Chen and Dr. Ji-zi Liu from Nanjing University of Science and Technology, investigated the mechanical properties and twinning behavior of CP-Ti at room temperature and liquid nitrogen temperature (LNT). “Studying the deformation behavior of CP-Ti and its alloys at cryogenic temperatures can help in the development of new controlled processes for improving their strength and ductility,” explains Dr. Chen about the motivation of their study. Their paper was made available online on December 20, 2023, and published in Volume 33, Issue 11 of the journal Transactions of Nonferrous Metals Society of China.

Using advanced techniques such as scanning electron backscatter diffraction and transmission electron microscopy, the researchers studied changes in the microstructure and dislocations of the CP-Ti samples under uniaxial loading at both temperatures. They investigated plastic hardening behavior, twinning-induced grain fragmentation, texture transformation, and plasticity of the samples.

Their experiments revealed that the recrystallized samples deformed at LNT exhibited a much better combination of strength and ductility than those deformed at room temperature. Moreover, at both temperatures, the sample with the smallest grain size showed the highest yield strength. Dislocation slip was identified as the main mechanism of deformation at room temperature, while deformation twinning became dominant at LNT. This transition of deformation mechanisms emerged as the main contributing factor to the outstanding mechanical properties observed at LNT. Furthermore, the team also proposed a modified Hall-Petch relationship accounting for cryogenic temperatures to explain the strengthening mechanism.

Dr. Liu emphasizes the importance of these findings, saying, “The results of the study provide important insights into the deformation processes of hexagonal metals at cryogenic temperatures. This can lead to improved processes for control and design of the metals that can withstand extreme conditions.”

Overall, this study enhances our understanding of the microstructure and deformation mechanisms of metals like Ti and paves the way for the development of stronger and more ductile metals.

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Reference

DOI: https://doi.org/10.1016/S1003-6326(23)66337-X

Authors: Cai Chen¹, Dong-sheng Han¹, Yu-tao Song², Ming-chuan Wang¹, Yu-sheng Li², Shun Xu³, Sen Yang⁴, Ji-zi Liu^2,5

Affiliations:

¹Sino-French Engineer School, Nanjing University of Science and Technology, China

²Nano and Heterogeneous Structural Materials Center, School of Materials Science and Engineering, Nanjing University of Science and Technology, China

³National Key Laboratory of Science and Technology on Materials under Shock and Impact, School of Materials Science and Engineering, Beijing Institute of Technology, China

⁴School of Materials Science and Engineering, Nanjing University of Science and Technology, China

⁵Center of Analytical Facilities, Nanjing University of Science and Technology, China

About Dr. Cai Chen

Cai Chen is currently an Assistant Professor at the Sino-French Engineer School at Nanjing University of Science and Technology (NJUST). His research includes severe plastic deformation, polycrystal plasticity, metal deformation and strengthening theory among others. Before joining NJUST, he served as a postdoctoral fellow at the University of Lorraine in France from 2016 to 2017. He has published more than 30 research papers in international peer-reviewed journals.