Cobalt-free battery for cleaner, greener power

High-capacity and reliable rechargeable batteries are a critical component of many devices and even modes of transport. They play a key role in the shift to a greener world. A wide variety of elements are used in their production, including cobalt, the production of which contributes to some environmental, economic, and social issues. For the first time, a team including researchers from the University of Tokyo presents a viable alternative to cobalt which in some ways can outperform state-of-the-art battery chemistry. It also survives a large number of recharge cycles, and the underlying theory can be applied to other problems.

The chances are, you are reading this article on a laptop or smartphone, and if not, you probably own at least one of those. Inside either device, and many others, you will find a lithium-ion battery (LIB). For decades now, LIBs have been the standard way of powering portable or mobile electronic devices and machines. As the world transitions from fossil fuels, they are seen as an important step for use in electric cars and home batteries for those with solar panels. But just as batteries have a positive end and a negative end, LIBs have negative points set against their positive ones.

For one thing, although they are some of the most power-dense portable power sources available, many people wish that LIBs could yield a larger energy density to make them either last longer or power even more demanding machines. Also, they can survive a large number of recharge cycles, but they also degrade with time; it would be better for everyone if batteries could survive more recharge cycles and maintain their capacities for longer. But perhaps the most alarming problem with current LIBs lies in one of the elements used for their construction.

Cobalt is widely used for a key part of LIBs, the electrodes. All batteries work in a similar way: Two electrodes, one positive and one negative, promote the flow of lithium ions between them in what’s called the electrolyte when connected to an external circuit. Cobalt, however, is a rare element; so rare in fact that there is only one main source of it at present: a series of mines located in the Democratic Republic of Congo. Many issues have been reported over the years about the environmental consequences of these mines, as well as the labor conditions there, including the use of child labor. From a supply perspective also, the source of cobalt is an issue due to political and economic instability in the region.

“There are many reasons we want to transition away from using cobalt in order to improve lithium-ion batteries,” said Professor Atsuo Yamada from the Department of Chemical System Engineering. “For us the challenge is a technical one, but its impact could be environmental, economic, social and technological. We are pleased to report a new alternative to cobalt by using a novel combination of elements in the electrodes, including lithium, nickel, manganese, silicon and oxygen — all far more common and less problematic elements to produce and work with.”

The new electrodes and electrolyte Yamada and his team created are not only devoid of cobalt, but they actually improve upon current battery chemistry in some ways. The new LIBs’ energy density is about 60% higher, which could equate to longer life, and it can deliver 4.4 volts, as opposed to about 3.2-3.7 volts of typical LIBs. But one of the most surprising technological achievements was to improve upon the recharge characteristics. Test batteries with the new chemistry were able to fully charge and discharge over 1,000 cycles (simulating three years of full use and charging), whilst only losing about 20% of their storage capacity.

“We are delighted with the results so far, but getting here was not without its challenges. It was a struggle trying to suppress various undesirable reactions that were taking place in early versions of our new battery chemistries which could have drastically reduced the longevity of the batteries,” said Yamada. “And we still have some way to go, as there are lingering minor reactions to mitigate in order to improve the safety and longevity even further. At present, we are confident that this research will lead to improved batteries for many applications, but some, where extreme durability and lifespan are required, might not be satisfied just yet.”

Although Yamada and his team were exploring applications in LIBs, the concepts that underlie their recent development can be applied to other electrochemical processes and devices, including other kinds of batteries, water splitting (to produce hydrogen and oxygen), ore smelting, electro-coating and more.

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Journal article: Seongjae Ko, Xiao Han, Tatau Shimada, Norio Takenaka, Yuki Yamada, and Atsuo Yamada, “Electrolyte design for lithium-ion batteries with cobalt free cathode and silicon oxide anode”, Nature Sustainability, https://doi.org/10.1038/s41893-023-01237-y

Funding:
This work was supported by the Japan Society for the Promotion of Science Grant-in Aid for Scientific Research S (A.Y.; Grant Number 20H05673), the Japan Science and Technology Agency Program on Open Innovation Platform for Industry-Academia Co-Creation (A.Y.; COI-NEXT, Grant Number JPMJPF1234), and the Ministry of Education, Culture, Sports, Science, and Technology (MEXT) Program: Data Creation and Utilization Type Materials Research and Development Project (A.Y.; Grant Number JPMXP1121467561). Y.Y. and S.K were supported by KAKENHI Grant Numbers 16H06368 and 21K20480. S.K. also acknowledges financial support from the Murata Science Foundation.

Useful links:
Department of Chemical System Engineering https://www.chemsys.t.u-tokyo.ac.jp/?lang=en Graduate School of Engineering https://www.t.u-tokyo.ac.jp/en/soe  

Research contact:
Professor Atsuo Yamada
Graduate School of Engineering, The University of Tokyo,
7-3-1 Hongo, Bunkyo-ku, Tokyo, 113-0033, Japan
[email protected]

Press contact:
Mr. Rohan Mehra
Public Relations Group, The University of Tokyo,
7-3-1 Hongo, Bunkyo-ku, Tokyo, 113-8656, Japan
[email protected]

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