3D insights into an innovative manufacturing process

3D printing can produce highly complex shapes. But printing ceramic objects with the help of a laser is a more difficult challenge. Now researchers at the Paul Scherrer Institute PSI have for the first time taken tomograms revealing what happens at microscopic level during this fabrication process. The findings will help improve this very promising technology.

3D printing is already being used to produce many objects. Additive manufacturing is increasingly being used in the aerospace and automotive industry, for example, as well as in medicine. The method commonly used for metals and plastics is known as laser-based powder bed fusion (LPBF). In LPBF, the material is applied as a fine powder layer on a substrate and then the laser passes over the powder and melts it to form it into the desired shape. The next thin layer of powder is deposited and once again melted by the laser. The component is built up sequentially in this way, layer by layer.

Exactly what happens during the LPBF process has already been investigated using X-rays at the Swiss Light Source SLS at PSI and fellow research institutes,  but these microscopic insights have only provided 2D images to date. “We wanted to go one step further and track the manufacturing process in 3D,” says Malgorzata Makowska, material scientist at PSI. Instead of 2D X-ray images, the researchers wanted to obtain 3D tomograms with a speed allowing to follow the laser spot. To do so, they had to rotate their sample during the manufacturing process and track this rapid rotary movement with the laser – a major challenge. For the first time, the team has now managed to do this, as reported in the journal Communications Materials.

Magnet stabilises a rotating precursor powder

The scientists used aluminium oxide for their experiments. This ceramic material is typically used, for example, in the chemical industry for components exposed to high temperatures, in electrical engineering as an insulator, or in medicine for implants. Because this material is extremely hard and brittle, however, fabricating complex shapes with conventional technology presents huge challenges. “It would be much easier if one could print such components,” says PSI physicist Steven Van Petegem: “When printing aluminium oxide, however, it’s still difficult to obtain a sufficiently dense material and the desired microstructure.”

The experiments conducted at the SLS tomography beamline TOMCAT offered new insights into the innovative manufacturing process. The test sample rotated at a speed of 50 Hz (3000 rpm), while the laser travelled over the powder. Adapting the printing process to this extremely rapid rotation was one of the main difficulties, which the researchers have now overcome. Another challenge was to prevent the rotating material drifting apart as a result of centrifugal forces. They achieved it by adding a tiny amount of magnetic iron oxide into the aluminium oxide powder particles and then incorporating a magnet to keep the powder in place. The magnet was mounted beneath the sample in a small cylinder with a 3 mm diameter.

“Thanks to the fast GigaFRoST camera, an in-house PSI development, and a highly efficient microscope, it was possible to acquire 100 3D images each second during the printing process”, explains beamline scientist Federica Marone. These images showed what happened to the powder during the laser treatment. “For the first time we were able to directly visualise the melted volume in 3D,” says Makowska. The shape of the so-called ‘melt pool’ surprised the researchers. When they increased the power of the laser, no depression formed on the surface, as expected. “Instead the melt pool spread out like a pancake and the surface was more or less flat,” the material scientist comments.

Printing the desired microstructure

The researchers could also observe how pores and hollows formed as the material hardened, which is important for future applications. “Ideally one would like to have a smooth, attractive material with a well-defined microstructure. But a certain amount of porosity is also very desirable for specific applications,” explains Makowska. Van Petegem adds: “We hope our experiments will reveal more about the printing process and that we can pass on this knowledge, so that it can be put to practical use, even if there is still a long way to go.” The upgrade of the SLS machine starting soon and the new TOMCAT 2.0 beamlines coming into operation in 2025 will enhance the current capabilities. “It will become possible to study denser material with higher spatial and temporal resolution, key aspects for bringing the LPBF technology further,” says beamline scientist Christian Schlepütz.

The study was made with the collaboration of the technology competence centre Inspire AG, ETH Zurich and Empa. It was funded by the Swiss National Science Foundation (SNSF) as a Spark project. The idea for this research was a follow-up of the Fuorclam project launched in 2017 within the frame of a Strategic Focus Area (SFA) Advanced Manufacturing program. “The various projects have given us the opportunity to get to know all the groups in Switzerland engaged in research into additive manufacturing and 3D printing,” says Van Petegem. “This is an extremely important topic for the future, which Switzerland has acknowledged.”

Text: Barbara Vonarburg

About PSI

The Paul Scherrer Institute PSI develops, builds and operates large, complex research facilities and makes them available to the national and international research community. The institute’s own key research priorities are in the fields of matter and materials, energy and environment and human health. PSI is committed to the training of future generations. Therefore about one quarter of our staff are post-docs, post-graduates or apprentices. Altogether PSI employs 2200 people, thus being the largest research institute in Switzerland. The annual budget amounts to approximately CHF 420 million. PSI is part of the ETH Domain, with the other members being the two Swiss Federal Institutes of Technology, ETH Zurich and EPFL Lausanne, as well as Eawag (Swiss Federal Institute of Aquatic Science and Technology), Empa (Swiss Federal Laboratories for Materials Science and Technology) and WSL (Swiss Federal Institute for Forest, Snow and Landscape Research). Insight into the exciting research of the PSI with changing focal points is provided 3 times a year in the publication 5232 – The Magazine of the Paul Scherrer Institute.

Contact

Dr. Małgorzata Grażyna Makowska

Advanced Nuclear Materials

Paul Scherrer Institute, Forschungsstrasse 111, 5232 Villigen PSI, Switzerland

Telephone: +41 56 310 45 36, e-mail: [email protected]

Dr. Steven Van Petegem

Structure and Mechanics of New Materials

Paul Scherrer Institute, Forschungsstrasse 111, 5232 Villigen PSI, Switzerland

Telephone: +41 56 310 25 37, e-mail: [email protected]

Dr. Federica Marone

X-ray Tomography

Paul Scherrer Institute, Forschungsstrasse 111, 5232 Villigen PSI, Switzerland

Telephone: +41 56 310 53 18, e-mail: [email protected]

Original publication

Operando tomographic microscopy during laser-based powder bed fusion

M. Makowska, F. Verga, S. Pfeiffer, F. Marone, C. Chang, C. Schlepütz, K. Florio, K. Wegener, T. Graule, S. Van Petegem

Communications Materials, 18.09.2023

DOI: 10.1038/s43246-023-00401-3