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	<title>unnatural prolines &#8211; BIOENGINEER.ORG</title>
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	<title>unnatural prolines &#8211; BIOENGINEER.ORG</title>
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		<title>Radical Enzyme Cascade Enables Stereoselective Unnatural Prolines</title>
		<link>https://bioengineer.org/radical-enzyme-cascade-enables-stereoselective-unnatural-prolines/</link>
		
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		<pubDate>Thu, 25 Sep 2025 15:54:08 +0000</pubDate>
				<category><![CDATA[Chemistry]]></category>
		<category><![CDATA[enzyme-mediated radical chemistry]]></category>
		<category><![CDATA[non-canonical amino acids]]></category>
		<category><![CDATA[photobiocatalytic cascade]]></category>
		<category><![CDATA[stereoselective synthesis]]></category>
		<category><![CDATA[unnatural prolines]]></category>
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					<description><![CDATA[In a groundbreaking advancement at the intersection of enzymology and synthetic chemistry, researchers have unveiled a pioneering photobiocatalytic cascade approach that dramatically enhances the stereoselective synthesis of unnatural prolines—complex amino acid derivatives with significant implications in pharmaceutical and material sciences. This innovative strategy bridges the gap between natural enzymatic pathways and engineered radical reactions, achieving [&#8230;]]]></description>
		
		
		
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