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	<title>redox-neutral synthesis &#8211; BIOENGINEER.ORG</title>
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	<title>redox-neutral synthesis &#8211; BIOENGINEER.ORG</title>
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		<title>Weakened O–H Bonds: Silicon Trick Unlocks Direct Hydrogen Atom Transfer for Chiral Alcohol Synthesis</title>
		<link>https://bioengineer.org/weakened-o-h-bonds-silicon-trick-unlocks-direct-hydrogen-atom-transfer-for-chiral-alcohol-synthesis/</link>
		
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		<pubDate>Mon, 12 Oct 2026 17:10:36 +0000</pubDate>
				<category><![CDATA[Chemistry]]></category>
		<category><![CDATA[acyloins]]></category>
		<category><![CDATA[bond dissociation energy]]></category>
		<category><![CDATA[Brook rearrangement]]></category>
		<category><![CDATA[enantioconvergent coupling]]></category>
		<category><![CDATA[hydrogen atom transfer]]></category>
		<category><![CDATA[nickel catalysis]]></category>
		<category><![CDATA[photocatalysis]]></category>
		<category><![CDATA[radical chemistry]]></category>
		<category><![CDATA[redox-neutral synthesis]]></category>
		<category><![CDATA[thioxanthone]]></category>
		<category><![CDATA[α-silyl alcohols]]></category>
		<category><![CDATA[β-silicon effect]]></category>
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					<description><![CDATA[Chemists at Wuhan University have harnessed the β-silicon effect to weaken the O–H bonds of α-silyl alcohols, enabling direct photoinduced hydrogen atom transfer and enantioconvergent nickel-catalyzed couplings that work even on substrates inert to classical electron-transfer methods.]]></description>
		
		
		
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