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	<title>Homoallylic alcohols &#8211; BIOENGINEER.ORG</title>
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	<title>Homoallylic alcohols &#8211; BIOENGINEER.ORG</title>
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		<title>Catalytic Enantioselective [1,2]-Wittig Rearrangement Breakthrough</title>
		<link>https://bioengineer.org/catalytic-enantioselective-12-wittig-rearrangement-breakthrough/</link>
		
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		<pubDate>Wed, 07 Jan 2026 06:42:04 +0000</pubDate>
				<category><![CDATA[Chemistry]]></category>
		<category><![CDATA[Cascade mechanism]]></category>
		<category><![CDATA[Enantioselective catalysis]]></category>
		<category><![CDATA[Homoallylic alcohols]]></category>
		<category><![CDATA[Synthetic methodology]]></category>
		<category><![CDATA[Wittig rearrangement]]></category>
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					<description><![CDATA[In a groundbreaking development poised to reshape synthetic organic chemistry, researchers have unveiled a novel catalytic cascade that achieves an enantioselective [1,2]-Wittig rearrangement of allylic ethers with unprecedented precision. This method, facilitated by a chiral tert-butyl-BIMP catalyst, provides access to enantioenriched homoallylic tertiary alcohols, compounds of significant value for pharmaceutical and fine chemical synthesis, all [&#8230;]]]></description>
		
		
		
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