image:
Fig. 1: Photographs of the utilized microscopes. Left: The 3 metres high, scanning transmission electron microscope Nion Ultra STEM 100 by Bruker Corporation. Right: View into the airless chamber containing the microscope AFSEM by Quantum Design GmbH.
view more
Credit: Wael Joudi, Jani Kotakoski
Graphene is a “miracle material”: mechanically extremely strong and electrically highly conductive, ideal for related applications. Using a worldwide unique method physicists at the University of Vienna led by Jani Kotakoski have for the first time made graphene drastically more stretchable by rippling it like an accordion. This paves the way for new applications in which certain stretchability is required (e.g. wearable electronics). In a collaboration with the Vienna University of Technology the exact mechanism of this phenomenon has been revealed and published in the journal Physical Review Letters.
The first experimental evidence of graphene in 2004 established a completely new class of materials, the so-called two-dimensional (2D) solids. Their name stems from the fact that they are only a single layer of atoms thick, giving rise to exotic material properties that could benefit various areas of application. Graphene for example stands out with its enormous electrical conductivity, but it is also very stiff. This extreme stiffness is a result of the honeycomb-shaped arrangement of the atoms in the material. Intuitively, the removal of some atoms from the material alongside their bonds should lead to a reduction in stiffness. However, scientific studies have reported both a slight reduction as well as a significant increase.
These contradictions have now been clarified through new measurements conducted by researchers of the group led by Jani Kotakoski at the University of Vienna. The experiments were carried out with state-of-the-art devices all sharing the same ultra-clean airless environment. This allows transporting samples between the different devices without ever being exposed to ambient air. “This unique system we have developed in the University of Vienna allows us to examine 2D materials without interference,” explains Jani Kotakoski. Wael Joudi, first author of the study adds: “For the first time this kind of experiment has been carried out with the graphene fully isolated from ambient air and the foreign particles it contains. Without this separation, these particles would quickly settle on the surface affecting the experiment procedure and measurements.”
In fact, the focus on meticulous cleanliness of the material surface led to the discovery of the so-called accordion effect with regard to the stiffness of graphene: already the removal of two neighbouring atoms leads to discernible bulging of the initially flat material. Several bulges together result in a corrugation of the material: “You can imagine it like an accordion. When pulled apart, the waved material now gets flattened, which requires much less force than stretching the flat material and therefore it becomes more stretchable,” explains Wael Joudi. Simulations carried out by the theoretical physicists Rika Saskia Windisch and Florian Libisch from the Vienna University of Technology confirm both the formation of waves and the resulting stretchability.
The experiments also showed that foreign particles on the material surface not only supress this effect, but lead to the opposite result. Specifically, their influence makes the material appear stiffer, which also explains contradictions of the past. “This shows the importance of the measurement environment when dealing with 2D materials. The results open up a way to regulate the stiffness of graphene and thus pave the way for potential applications,” concludes Wael Joudi.
The research was funded in whole or in part by the Austrian Science Fund (FWF).
Journal
Physical Review Letters
DOI
10.1103/PhysRevLett.134.166102
Article Title
Corrugation-Dominated Mechanical Softening of Defect-Engineered Graphene
Article Publication Date
25-Apr-2025
Media Contact
Theresa Bittermann
University of Vienna
Journal
Physical Review Letters
DOI
10.1103/PhysRevLett.134.166102
Article Title
Corrugation-Dominated Mechanical Softening of Defect-Engineered Graphene
Article Publication Date
25-Apr-2025
bu içeriği en az 2000 kelime olacak şekilde ve alt başlıklar ve madde içermiyecek şekilde ünlü bir science magazine için İngilizce olarak yeniden yaz. Teknik açıklamalar içersin ve viral olacak şekilde İngilizce yaz. Haber dışında başka bir şey içermesin. Haber içerisinde en az 12 paragraf ve her bir paragrafta da en az 50 kelime olsun. Cevapta sadece haber olsun. Ayrıca haberi yazdıktan sonra içerikten yararlanarak aşağıdaki başlıkların bilgisi var ise haberin altında doldur. Eğer yoksa bilgisi ilgili kısmı yazma.:
Subject of Research:
Article Title:
News Publication Date:
Web References:
References:
Image Credits:
Keywords
Tags: accordion effect in materialsapplications of graphene technologyelectrically conductive graphenegraphene stretchability advancementsinnovative materials for engineeringmaterial science breakthroughsmechanically strong materialsnew uses for graphenephysicists studying graphenerippling graphene techniquestretchable electronic devicesUniversity of Vienna graphene research